Zachodniopomorski Uniwersytet Technologiczny w Szczecinie

Wydział Technologii i Inżynierii Chemicznej - Chemical Engineering (S1)

Sylabus przedmiotu Kinetics and Catalysis of Chemical Reactions:

Informacje podstawowe

Kierunek studiów Chemical Engineering
Forma studiów studia stacjonarne Poziom pierwszego stopnia
Tytuł zawodowy absolwenta inżynier
Obszary studiów charakterystyki PRK, kompetencje inżynierskie PRK
Profil ogólnoakademicki
Moduł —
Przedmiot Kinetics and Catalysis of Chemical Reactions
Specjalność przedmiot wspólny
Jednostka prowadząca Katedra Technologii Chemicznej Nieorganicznej i Inżynierii Środowiska
Nauczyciel odpowiedzialny Rafał Wróbel <Rafal.Wrobel@zut.edu.pl>
Inni nauczyciele Rafał Wróbel <Rafal.Wrobel@zut.edu.pl>
ECTS (planowane) 5,0 ECTS (formy) 5,0
Forma zaliczenia egzamin Język angielski
Blok obieralny — Grupa obieralna —

Formy dydaktyczne

Forma dydaktycznaKODSemestrGodzinyECTSWagaZaliczenie
wykładyW3 30 2,50,50egzamin
laboratoriaL3 30 2,50,50zaliczenie

Wymagania wstępne

KODWymaganie wstępne
W-1Basic chemistry and advanced mathematics

Cele przedmiotu

KODCel modułu/przedmiotu
C-1Getting knowledge about kinetics of chemical reactions, catalysis and related calculations

Treści programowe z podziałem na formy zajęć

KODTreść programowaGodziny
laboratoria
T-L-1Hydrothermal synthesis of TS-1 zeolite, its activation and acidity studies5
T-L-2Epoxidation of allyl alcohol over the TS-1 zeolite catalyst5
T-L-3Impact of poisoning of catalyst on reaction kinetic.5
T-L-4Catalytic carbon monoxide oxidation5
T-L-5Catalytic ammonia decomposition5
T-L-6Determination of the ion-exchange capacity of porous materials5
30
wykłady
T-W-1Definitions and Concepts - Rate of Reaction; Turnover Frequency; Selectivity; Elementary Step and Rate Determining Step (RDS); Reaction Rates in Reactors; Metal Dispersion; Metal-Support Interactions (MSI)3
T-W-2Catalyst Characterization2
T-W-3Acquisition and Evaluation of Reaction Rate Data - Types of Reactors; Heat and Mass Transfer Effects; Intraphase Gradients; Criteria to Verify the Absence of Mass and Heat Transfer Limitations3
T-W-4Adsorption and Desorption Processes - Adsorption Rate; Desorption Rate; Adsorption Equilibrium on Uniform Surfaces-Langmuir Isotherms; Adsorption Equilibrium on Nonuniform (Nonideal) Surfaces; Activated Adsorption3
T-W-5Kinetic Data Analysis - Transition-State Theory (TST) or Absolute Rate Theory; The Steady-State Approximation (SSA); Heats of Adsorption and Activation Barriers on; Use of a Rate Determining Step (RDS) and/or a Most Abundant Reaction Intermediate (MARI)3
T-W-6. Modeling Reactions on Uniform (Ideal) Surfaces - Reaction Models with a RDS – Unimolecular Surface Reactions; Reaction Models with a RDS – Bimolecular Surface Reactions; Reaction Models with a RDS – Reactions between an Adsorbed Species and a Gas-Phase Species; Reaction Models with no RDS; A Series of Irreversible Steps – General; Data Analysis with an Integral Reactor;3
T-W-7Modeling Reactions on Nonuniform (Nonideal) Surfaces - Initial Models of a Nonuniform Surface; Correlations in Kinetics; Formalism of a Temkin Surface; Consequences of Temkin’s Model;2
T-W-8Kinetics of Enzyme-Catalyzed Reactions1
T-W-9Selection of heterogeneous catalyst for the reactions in organic technology.10
30

Obciążenie pracą studenta - formy aktywności

KODForma aktywnościGodziny
laboratoria
A-L-1Participation laboratory classes30
A-L-2Reading the literature13
A-L-3Preparation of raports17
A-L-4Consultations3
63
wykłady
A-W-1Obligatory attendance the lactures30
A-W-2Exam2
A-W-3Reading the literature17
A-W-4Homeworks12
A-W-5Consultations2
63

Metody nauczania / narzędzia dydaktyczne

KODMetoda nauczania / narzędzie dydaktyczne
M-1Lecture
M-2laboratory

Sposoby oceny

KODSposób oceny
S-1Ocena podsumowująca: Written exam
S-2Ocena podsumowująca: raport
S-3Ocena formująca: activity

Zamierzone efekty uczenia się - wiedza

Zamierzone efekty uczenia sięOdniesienie do efektów kształcenia dla kierunku studiówOdniesienie do efektów zdefiniowanych dla obszaru kształceniaOdniesienie do efektów uczenia się prowadzących do uzyskania tytułu zawodowego inżynieraCel przedmiotuTreści programoweMetody nauczaniaSposób oceny
ChEn_1A_C07_W01
Student knows the theorem of catalysis and its applications in chemical engineering. He or she also knows typical catalytic chemical industrial processes.		ChEn_1A_W10, ChEn_1A_W20——C-1T-W-1, T-W-2, T-W-3, T-W-4, T-W-5, T-W-6, T-W-7, T-W-8, T-W-9M-1S-1

Zamierzone efekty uczenia się - umiejętności

Zamierzone efekty uczenia sięOdniesienie do efektów kształcenia dla kierunku studiówOdniesienie do efektów zdefiniowanych dla obszaru kształceniaOdniesienie do efektów uczenia się prowadzących do uzyskania tytułu zawodowego inżynieraCel przedmiotuTreści programoweMetody nauczaniaSposób oceny
ChEn_1A_C07_U01
Student is able to find literature data required for evaluation of catalytic processes with modern data bases and search engines. He or she is also able to plan experiments with catalytic reaction and choose the appropriate control techniques.		ChEn_1A_U03, ChEn_1A_U05, ChEn_1A_U08, ChEn_1A_U10, ChEn_1A_U16, ChEn_1A_U07, ChEn_1A_U01——C-1T-L-3, T-L-4, T-L-5, T-L-1, T-L-2, T-L-6M-2S-2

Zamierzone efekty uczenia się - inne kompetencje społeczne i personalne

Zamierzone efekty uczenia sięOdniesienie do efektów kształcenia dla kierunku studiówOdniesienie do efektów zdefiniowanych dla obszaru kształceniaOdniesienie do efektów uczenia się prowadzących do uzyskania tytułu zawodowego inżynieraCel przedmiotuTreści programoweMetody nauczaniaSposób oceny
ChEn_1A_C07_K01
Student is able to teamwork focused on solving catalytically problems. He or she is understand the requirement of self-development in mastering the skills of catalytical processes in chemical engineering.		ChEn_1A_K04, ChEn_1A_K05, ChEn_1A_K01, ChEn_1A_K03——C-1T-W-1, T-W-2, T-W-3, T-W-4, T-W-5, T-W-6, T-W-7, T-W-8, T-W-9, T-L-3, T-L-4, T-L-5, T-L-1, T-L-2, T-L-6M-1, M-2S-3

Kryterium oceny - wiedza

Efekt uczenia sięOcenaKryterium oceny
ChEn_1A_C07_W01
Student knows the theorem of catalysis and its applications in chemical engineering. He or she also knows typical catalytic chemical industrial processes.		2,0
3,0Student correctly prepared project and solved at least 60% of problems.
3,5
4,0
4,5
5,0

Kryterium oceny - umiejętności

Efekt uczenia sięOcenaKryterium oceny
ChEn_1A_C07_U01
Student is able to find literature data required for evaluation of catalytic processes with modern data bases and search engines. He or she is also able to plan experiments with catalytic reaction and choose the appropriate control techniques.		2,0
3,0Student can calculate the rate of basic reactions
3,5
4,0
4,5
5,0

Kryterium oceny - inne kompetencje społeczne i personalne

Efekt uczenia sięOcenaKryterium oceny
ChEn_1A_C07_K01
Student is able to teamwork focused on solving catalytically problems. He or she is understand the requirement of self-development in mastering the skills of catalytical processes in chemical engineering.		2,0
3,0Student is able to teamwork in problem solving
3,5
4,0
4,5
5,0

Literatura podstawowa

  1. M. Albert Vannice, Kinetics of Catalytic Reactions, Springer, 2005

Treści programowe - laboratoria

KODTreść programowaGodziny
T-L-1Hydrothermal synthesis of TS-1 zeolite, its activation and acidity studies5
T-L-2Epoxidation of allyl alcohol over the TS-1 zeolite catalyst5
T-L-3Impact of poisoning of catalyst on reaction kinetic.5
T-L-4Catalytic carbon monoxide oxidation5
T-L-5Catalytic ammonia decomposition5
T-L-6Determination of the ion-exchange capacity of porous materials5
30

Treści programowe - wykłady

KODTreść programowaGodziny
T-W-1Definitions and Concepts - Rate of Reaction; Turnover Frequency; Selectivity; Elementary Step and Rate Determining Step (RDS); Reaction Rates in Reactors; Metal Dispersion; Metal-Support Interactions (MSI)3
T-W-2Catalyst Characterization2
T-W-3Acquisition and Evaluation of Reaction Rate Data - Types of Reactors; Heat and Mass Transfer Effects; Intraphase Gradients; Criteria to Verify the Absence of Mass and Heat Transfer Limitations3
T-W-4Adsorption and Desorption Processes - Adsorption Rate; Desorption Rate; Adsorption Equilibrium on Uniform Surfaces-Langmuir Isotherms; Adsorption Equilibrium on Nonuniform (Nonideal) Surfaces; Activated Adsorption3
T-W-5Kinetic Data Analysis - Transition-State Theory (TST) or Absolute Rate Theory; The Steady-State Approximation (SSA); Heats of Adsorption and Activation Barriers on; Use of a Rate Determining Step (RDS) and/or a Most Abundant Reaction Intermediate (MARI)3
T-W-6. Modeling Reactions on Uniform (Ideal) Surfaces - Reaction Models with a RDS – Unimolecular Surface Reactions; Reaction Models with a RDS – Bimolecular Surface Reactions; Reaction Models with a RDS – Reactions between an Adsorbed Species and a Gas-Phase Species; Reaction Models with no RDS; A Series of Irreversible Steps – General; Data Analysis with an Integral Reactor;3
T-W-7Modeling Reactions on Nonuniform (Nonideal) Surfaces - Initial Models of a Nonuniform Surface; Correlations in Kinetics; Formalism of a Temkin Surface; Consequences of Temkin’s Model;2
T-W-8Kinetics of Enzyme-Catalyzed Reactions1
T-W-9Selection of heterogeneous catalyst for the reactions in organic technology.10
30

Formy aktywności - laboratoria

KODForma aktywnościGodziny
A-L-1Participation laboratory classes30
A-L-2Reading the literature13
A-L-3Preparation of raports17
A-L-4Consultations3
63
(*) 1 punkt ECTS, odpowiada około 30 godzinom aktywności studenta

Formy aktywności - wykłady

KODForma aktywnościGodziny
A-W-1Obligatory attendance the lactures30
A-W-2Exam2
A-W-3Reading the literature17
A-W-4Homeworks12
A-W-5Consultations2
63
(*) 1 punkt ECTS, odpowiada około 30 godzinom aktywności studenta
PoleKODZnaczenie kodu
Zamierzone efekty uczenia sięChEn_1A_C07_W01Student knows the theorem of catalysis and its applications in chemical engineering. He or she also knows typical catalytic chemical industrial processes.
Odniesienie do efektów kształcenia dla kierunku studiówChEn_1A_W10Has systematic, theory-based knowledge of the kinetics of physical and chemical transformation processes, thermodynamics and engineering of chemical reactors.
ChEn_1A_W20Knows the functioning of typical processes in chemical engineering and technology.
Cel przedmiotuC-1Getting knowledge about kinetics of chemical reactions, catalysis and related calculations
Treści programoweT-W-1Definitions and Concepts - Rate of Reaction; Turnover Frequency; Selectivity; Elementary Step and Rate Determining Step (RDS); Reaction Rates in Reactors; Metal Dispersion; Metal-Support Interactions (MSI)
T-W-2Catalyst Characterization
T-W-3Acquisition and Evaluation of Reaction Rate Data - Types of Reactors; Heat and Mass Transfer Effects; Intraphase Gradients; Criteria to Verify the Absence of Mass and Heat Transfer Limitations
T-W-4Adsorption and Desorption Processes - Adsorption Rate; Desorption Rate; Adsorption Equilibrium on Uniform Surfaces-Langmuir Isotherms; Adsorption Equilibrium on Nonuniform (Nonideal) Surfaces; Activated Adsorption
T-W-5Kinetic Data Analysis - Transition-State Theory (TST) or Absolute Rate Theory; The Steady-State Approximation (SSA); Heats of Adsorption and Activation Barriers on; Use of a Rate Determining Step (RDS) and/or a Most Abundant Reaction Intermediate (MARI)
T-W-6. Modeling Reactions on Uniform (Ideal) Surfaces - Reaction Models with a RDS – Unimolecular Surface Reactions; Reaction Models with a RDS – Bimolecular Surface Reactions; Reaction Models with a RDS – Reactions between an Adsorbed Species and a Gas-Phase Species; Reaction Models with no RDS; A Series of Irreversible Steps – General; Data Analysis with an Integral Reactor;
T-W-7Modeling Reactions on Nonuniform (Nonideal) Surfaces - Initial Models of a Nonuniform Surface; Correlations in Kinetics; Formalism of a Temkin Surface; Consequences of Temkin’s Model;
T-W-8Kinetics of Enzyme-Catalyzed Reactions
T-W-9Selection of heterogeneous catalyst for the reactions in organic technology.
Metody nauczaniaM-1Lecture
Sposób ocenyS-1Ocena podsumowująca: Written exam
Kryteria ocenyOcenaKryterium oceny
2,0
3,0Student correctly prepared project and solved at least 60% of problems.
3,5
4,0
4,5
5,0
PoleKODZnaczenie kodu
Zamierzone efekty uczenia sięChEn_1A_C07_U01Student is able to find literature data required for evaluation of catalytic processes with modern data bases and search engines. He or she is also able to plan experiments with catalytic reaction and choose the appropriate control techniques.
Odniesienie do efektów kształcenia dla kierunku studiówChEn_1A_U03Is able to prepare, in English or another foreign language, a well-documented study of problems within the scope of chemical and process engineering; is able to develop documentation concerning the accomplishment of an engineering task.
ChEn_1A_U05Has the ability to learn, e.g. to raise professional competences.
ChEn_1A_U08Is able to plan and conduct process experiments, including measurements and computer simulations, as well as to interpret the obtained results and draw conclusions.
ChEn_1A_U10Based on general knowledge, is able to explain basic phenomena connected with significant processes in chemical engineering and technology.
ChEn_1A_U16Is able to assess the usefulness of routine methods and tools used for solving a simple engineering task of practical nature characteristic for chemical engineering and technology as well as select and use a proper performance method and tools.
ChEn_1A_U07Is able to use computer programs supporting the accomplishment of basic engineering tasks.
ChEn_1A_U01Is able to obtain information from literature, data bases and other sources related to chemical engineering and technology as well as related areas; is able to integrate the obtained information, interpret it, draw proper conclusions and formulate opinions with their justification.
Cel przedmiotuC-1Getting knowledge about kinetics of chemical reactions, catalysis and related calculations
Treści programoweT-L-3Impact of poisoning of catalyst on reaction kinetic.
T-L-4Catalytic carbon monoxide oxidation
T-L-5Catalytic ammonia decomposition
T-L-1Hydrothermal synthesis of TS-1 zeolite, its activation and acidity studies
T-L-2Epoxidation of allyl alcohol over the TS-1 zeolite catalyst
T-L-6Determination of the ion-exchange capacity of porous materials
Metody nauczaniaM-2laboratory
Sposób ocenyS-2Ocena podsumowująca: raport
Kryteria ocenyOcenaKryterium oceny
2,0
3,0Student can calculate the rate of basic reactions
3,5
4,0
4,5
5,0
PoleKODZnaczenie kodu
Zamierzone efekty uczenia sięChEn_1A_C07_K01Student is able to teamwork focused on solving catalytically problems. He or she is understand the requirement of self-development in mastering the skills of catalytical processes in chemical engineering.
Odniesienie do efektów kształcenia dla kierunku studiówChEn_1A_K04Is able to determine the priorities used for performance of the tasks of his/her own or other team members in order to achieve the goal set.
ChEn_1A_K05Is able to manage his/her own professional development, taking decisions and solving problems, including interpersonal ones connected with job performance.
ChEn_1A_K01Understands the need of learning and raising professional and personal competences, motivating other colleagues.
ChEn_1A_K03Is able to cooperate and work in a group. Is able to perform the function of a team leader; is able to estimate the time necessary to accomplish the assigned task.
Cel przedmiotuC-1Getting knowledge about kinetics of chemical reactions, catalysis and related calculations
Treści programoweT-W-1Definitions and Concepts - Rate of Reaction; Turnover Frequency; Selectivity; Elementary Step and Rate Determining Step (RDS); Reaction Rates in Reactors; Metal Dispersion; Metal-Support Interactions (MSI)
T-W-2Catalyst Characterization
T-W-3Acquisition and Evaluation of Reaction Rate Data - Types of Reactors; Heat and Mass Transfer Effects; Intraphase Gradients; Criteria to Verify the Absence of Mass and Heat Transfer Limitations
T-W-4Adsorption and Desorption Processes - Adsorption Rate; Desorption Rate; Adsorption Equilibrium on Uniform Surfaces-Langmuir Isotherms; Adsorption Equilibrium on Nonuniform (Nonideal) Surfaces; Activated Adsorption
T-W-5Kinetic Data Analysis - Transition-State Theory (TST) or Absolute Rate Theory; The Steady-State Approximation (SSA); Heats of Adsorption and Activation Barriers on; Use of a Rate Determining Step (RDS) and/or a Most Abundant Reaction Intermediate (MARI)
T-W-6. Modeling Reactions on Uniform (Ideal) Surfaces - Reaction Models with a RDS – Unimolecular Surface Reactions; Reaction Models with a RDS – Bimolecular Surface Reactions; Reaction Models with a RDS – Reactions between an Adsorbed Species and a Gas-Phase Species; Reaction Models with no RDS; A Series of Irreversible Steps – General; Data Analysis with an Integral Reactor;
T-W-7Modeling Reactions on Nonuniform (Nonideal) Surfaces - Initial Models of a Nonuniform Surface; Correlations in Kinetics; Formalism of a Temkin Surface; Consequences of Temkin’s Model;
T-W-8Kinetics of Enzyme-Catalyzed Reactions
T-W-9Selection of heterogeneous catalyst for the reactions in organic technology.
T-L-3Impact of poisoning of catalyst on reaction kinetic.
T-L-4Catalytic carbon monoxide oxidation
T-L-5Catalytic ammonia decomposition
T-L-1Hydrothermal synthesis of TS-1 zeolite, its activation and acidity studies
T-L-2Epoxidation of allyl alcohol over the TS-1 zeolite catalyst
T-L-6Determination of the ion-exchange capacity of porous materials
Metody nauczaniaM-1Lecture
M-2laboratory
Sposób ocenyS-3Ocena formująca: activity
Kryteria ocenyOcenaKryterium oceny
2,0
3,0Student is able to teamwork in problem solving
3,5
4,0
4,5
5,0